Not quickly. The framework is recent and administered under executive action, so its terms can be adjusted, which means verifying them immediately before payment rather than at the moment of deciding. Any pending petition should be reviewed first, since decisions about it are hard to reverse.
Slow at the front, because there is no back
Timing advice here runs against the usual instinct. With most routes, moving early is an advantage because queues lengthen and documents take time. With an irreversible payment under a young framework, the advantage lies in sequence rather than speed.
First, establish what the household actually wants: residence, the ability to work, the ability to run a business, or simply to be present for part of the year. Second, review the existing petition with counsel and understand what withdrawing it would forfeit. Third, read the official programme page and the executive action as they stand, not as they were summarised.
Fourth, take tax advice, because becoming resident has consequences for an Ontario company and for an estate that no immigration adviser should be answering. Only then decide, and verify the terms again on the day money is to move. A decision that was correct last quarter may rest on wording that has since changed.